荧光粉
钨酸盐
发光
钼酸盐
掺杂剂
材料科学
热液循环
八面体
兴奋剂
分析化学(期刊)
矿物学
化学工程
化学
结晶学
晶体结构
光电子学
冶金
有机化学
工程类
作者
Yurong Shi,Bitao Liu,Chunyang Li,Wen Luo,Zhenling Wang
标识
DOI:10.1016/j.materresbull.2018.01.048
摘要
W6+ dopant on the NaLa(MoO4)2:Eu3+ solid solution phosphors with various shapes have been synthesized via the hydrothermal method without using any structural modifier and organic solvents. The morphology and luminescence properties of W6+ doped NaLa(MoO4)2:Eu3+ phosphors are obtained and characterized by SEM and PL/PLE spectra. Both morphology and luminescence properties are considered to manipulate by the mole ratio of W/Mo. By increasing the W6+ amount, particle shapes are changed from rice-shaped particles to spindle-shaped, cocoon-shaped, then to layers of octahedron-shaped. Under UV light excitation, all samples show bright red light due to the characteristic 4f-4f transitions of Eu3+. Tungstate and molybdate phosphors have higher luminescence intensity than that of tungstate and molybdate solid solution phosphors.
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