普鲁士蓝
材料科学
吸附
结晶度
氧化物
离子
蚀刻(微加工)
金属
水溶液中的金属离子
化学工程
纳米技术
复合材料
冶金
化学
电极
物理化学
有机化学
工程类
电化学
图层(电子)
作者
Jun Xu,Fanxing Bu,Yifei Guo,Wei Zhang,Ming Hu,Ji-Sen Jiang
标识
DOI:10.1166/jnn.2018.14546
摘要
Radioactive cesium pollution have received considerable attention due to the increasing risks in development of the nuclear power plants in the world. Although various functional porous materials are utilized to adsorb Cs+ ions in water, Prussian blue analogues (PBAs) are an impressive class of candidates because of their super affinity of Cs+ ions. The adsorption ability of the PBAs strongly relate to the mesostructure and interstitial sites. To design a hollow PBA with large number of interstitial sites, the traditional hollowing methods are not suitable owing to the difficulty in processing the specific PBAs with large number of interstitial sites. In this work, we empolyed a rational strategy which was to form a "metal oxide"@"PBA" core-shell structure via coordination replication at first, then utilized a mild etching to remove the metal oxide core, led to hollow PBA finally. The obtained hollow PBAs were of high crystallinity and large number of interstitial sites, showing a super adsorption performance for Cs+ ions (221.6 mg/g) within a short period (10 min).
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