Degradation of Dye Wastewater over NH2-UiO-66: Piezoelectrically Induced Mechano-Catalytic Effect

Metal-organic frameworks (MOF) as piezoelectrical materials used in mechano-catalytic degradation of organic dye are rarely investigated.In this work, NH 2 -UiO-66 was synthesized by the solvothermal method and applied in mechano-catalytic degradation of Rhodamine B under ultrasonic vibration.The results show that NH 2 -UiO-66 behaves a high mechano-catalytic decomposition efficiency of 80% for Rhodamine B within 5 h vibration and possesses a good stability.The piezoelectrically induced electric charges on the surfaces of NH 2 -UiO-66 via the piezoelectric effect could induce hydroxyl radicals as strong oxidants to decompose Rhodamine B. The piezoelectrical effect of MOFs is potential in utilizing vibration energy for dye wastewater treatment.