化学
硫黄
电合成
达布科
电化学
组合化学
辛烷值
转化(遗传学)
溶剂
有机化学
物理化学
电极
生物化学
基因
作者
Li‐Rong Wen,Ningning Wang,Wu‐Bo Du,Mingzhe Zhu,Chao Pan,Lin‐Bao Zhang,Ming Li
标识
DOI:10.1002/cjoc.202100132
摘要
Main observation and conclusion A general and practical protocol for the construction of diversified sulfur heterocycles has been described through organic electrosynthesis means. In undivided cell, dihydrothiophenes, thiazolines and 1,4‐dithiines could be easily generated from various available β‐ketothioamides under metal‐free and external oxidant‐free conditions. The transformation underwent smoothly under mild conditions and could be easily scaled‐up. Moreover, different sulfur heterocycles were generated through varying solvent and 1,4‐diazabicyclo[2.2.2]octane (DABCO) could enable the hydrogen atom transfer (HAT) process of this transformation.
科研通智能强力驱动
Strongly Powered by AbleSci AI