钙钛矿(结构)
材料科学
制作
光致发光
结晶
X射线探测器
光电子学
光电探测器
卤化物
离子
Crystal(编程语言)
探测器
光学
化学工程
化学
结晶学
无机化学
计算机科学
医学
替代医学
物理
病理
工程类
程序设计语言
有机化学
作者
Jiali Peng,Yalun Xu,Fang Yao,Huihuang Huang,Ruiming Li,Qianqian Lin
出处
期刊:Matter
[Elsevier]
日期:2022-07-01
卷期号:5 (7): 2251-2264
被引量:54
标识
DOI:10.1016/j.matt.2022.04.030
摘要
Metal-halide perovskites have recently emerged as promising candidates for next-generation X-ray detectors, mainly benefiting from their low-temperature solution processability, chemical versatility, low cost, and excellent and tunable optoelectronic properties. However, the fabrication of perovskite thick junctions is very challenging, particularly for solution-processed thick photodiodes. Here, we report an ion-exchange strategy to prepare two-dimensional (2D)-3D perovskite thick films for directly detecting X-rays. This approach provides a facile and generic fabrication of high-quality perovskite films with various perovskite precursors, achieving uniform morphology, tunable thickness, and vertically monolithic crystal phase. The dynamic processes of the ion exchange were fully characterized and studied with multiple in situ and ex situ techniques, e.g., photoluminescence spectroscopy and X-ray diffraction. After optimization, record-high X-ray sensitivity of 1.36 × 104 μC Gyair-1 cm-2 and ultra-low detection limit of 4.2 nGyair s-1 were achieved based on the optimized (BA2PbBr4)0.5FAPbI3 detectors, demonstrated along with 32 × 32 pixel prototypical photodetector arrays.
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