过硫酸盐
催化作用
纳米复合材料
罗丹明B
材料科学
高级氧化法
降级(电信)
单线态氧
激进的
二嗪酮
光化学
光降解
猝灭(荧光)
羟基自由基
化学工程
核化学
光催化
化学
杀虫剂
有机化学
纳米技术
氧气
荧光
工程类
物理
生物
电信
量子力学
计算机科学
农学
作者
Meghdad Pirsaheb,Hiwa Hossaini,Anvar Asadi,Borhan Mansouri,Zeinab Jafari Motlagh,Reza Jafari Motlagh
标识
DOI:10.1016/j.surfin.2022.102609
摘要
In the present study, the WO3CuO/RGO nanocomposite was fabricated for activating persulfate (PS) for organic pollutants degradation under visible-light irradiation. Several techniques were used for identification of catalyst features. The characterization results revealed the successful construction of the nanocomposite. The effects of operation factors influencing to the removal process were also studied. At optimal conditions (11 mg L−1 pollutant, nanocomposite 0.55 g L−1, PS concentration: 0.9 mM, pH: 5 and reaction time: for rhodamine B degradation (50 min) and for diazinon degradation (40 min)), diazinon and rhodamine B were completely degraded. Free radicals were detected during quenching experiments. Singlet oxygen (1O2), hydroxyl radical (OH•) and sulfate radical (SO4∙−) have an important role in the degradation process. A possible mechanism for PS activation was proposed. A significant potential was obtained in reusing of catalyst in four sequential runs. In conclusion, the WO3CuO/RGO-PS system can be applied as a promising process into efficient removal of organic pollutants due to high catalytic activity and high recyclability potential.
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