电致变色
发射率
红外线的
材料科学
光电子学
插层(化学)
电容感应
电化学
光电效应
光热治疗
超级电容器
纳米技术
光学
化学
电极
无机化学
物理化学
电气工程
物理
工程类
作者
Feifei Lu,Danni Shi,Peiyu Tan,Yuge Han
标识
DOI:10.1016/j.cej.2022.138324
摘要
Due to its unique two-dimensional structure, MXene has attracted extensive attention in the fields of electrochemical energy storage and conversion, photothermal conversion, and electromagnetic shielding. With the capacitive and photoelectric properties combined, an infrared electrochromic device based on Ti3C2Tx MXene is created and employed for dynamic thermal radiation regulation. The device exhibits dynamic emissivity variations of 0.31, 0.24, and 0.23 in the wavelength bands of 3–5 μm, 8–14 μm, and 2.5–18 μm, respectively. However, the regulation mechanism of MXene’s infrared emissivity is not clear. In this work, the morphology, structures, and electrochemical properties of MXene were characterized and analyzed. The results reveal that the reason for MXene's emissivity variation is related to the changes in the free O-terminal groups caused by Li-ion intercalation/deintercalation. This paper creates a new application of MXene in the field of dynamic regulation of thermal radiation.
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