Isoreticular Metal–Organic Frameworks with Aromatic Pores and Dimethylammonium Cations Enable Separation of Light Hydrocarbons and Xenon/Krypton

The separation of C2-C3 hydrocarbons from methane in natural gas and xenon/krypton purification are crucial yet challenging industrial processes. Herein, we report two isoreticular metal-organic frameworks, ZJU-89 and ZJU-90, featuring aromatic pore environments and dimethylammonium cations, that synergistically enhance the separation of these industrially relevant gas mixtures. ZJU-90 exhibits an exceptional separation performance, achieving C