Luminescence enhanced temperature sensor based on the up-conversion emission in Er3+/Yb3+/Mo6+ tri-doped tellurite fiber

In this study, the green up-conversion (UC) fluorescence emission in Er3+/Yb3+/Mo6+ tri-doped tellurite glasses (TeO2–ZnO–Li2CO3–Bi2O3, TZLB) was explored for temperature sensing. The doping of Mo6+ ions allowed enhanced luminescence at moderate power pumping, avoiding the introduction of undesired laser-induced thermal effects while improving the spectral signal-to-noise ratio. The luminescence characteristics were investigated in detail at different doping molar ratio of Mo6+ ions, and the strongest was observed at 8 mol%. Drawing on tri-doped TZLB glass with the strongest UC emission intensity, a tri-doped TZLB fiber was fabricated and coupled with two multimode fibers (MMFs) via Ultraviolet (UV) adhesive, forming the temperature sensor. The sensor was further encapsulated by a silica tube sealed with Ultraviolet adhesive, overcoming the poor mechanical property of tellurite fiber. The temperature information could be demodulated based on the fluorescence intensity ratio technique. The temperature sensing performance of the tri-doped TZLB sensor was investigated as temperature varied from 258 to 420 K and its repeatability was experimentally verified. The Er3+/Yb3+/Mo6+ tri-doped TZLB has an application prospect in the field of lighting, and the so-based temperature sensor is expected to be applied to thermal detection in the fields of medical diagnostics, environmental monitoring, and optical thermometers, etc.