光催化
异质结
材料科学
氢氧化物
光电流
X射线光电子能谱
电场
介电谱
化学工程
制氢
电子
氢
光化学
纳米技术
光电子学
化学
电化学
无机化学
电极
催化作用
物理化学
物理
工程类
有机化学
量子力学
作者
Bo Wen,Xin Guo,Yafeng Liu,Zhiliang Jin
出处
期刊:ACS applied nano materials
[American Chemical Society]
日期:2024-03-01
卷期号:7 (6): 6056-6067
被引量:4
标识
DOI:10.1021/acsanm.3c05962
摘要
Photocatalytic hydrogen evolution technology faces great challenges in designing efficient and stable hydrogen evolution catalysts that absorb visible light. In this study, a catalyst with S-scheme heterojunction and built-in electric fields was successfully prepared by electrostatic self-assembly to load ZnCdS nanoparticles on layered Ni–Co. The ZnCdS/NiCo layered double hydroxide (NiCo-LDH) test demonstrates that the S-scheme heterojunction and built-in electric fields effectively inhibit the recombination of photogenerated electrons and holes, lowering impedance and increasing photocurrent. Additionally, more photogenerated electrons can take part in the reduction reaction, producing more H2. It is worth noting that the hydrogen evolution of ZnCdS/NiCo-LDH is 1153 μmol in 5 h, which is 10 times that of ZnCdS. We analyze the electron transport process, construction of a built-in electric field, and formation of the S-scheme of this catalyst during hydrogen evolution by in situ X-ray photoelectron spectroscopy. This study provides a new perspective for the application of ZnCdS and LDH in photocatalysis and a new direction for the breakthrough of photocatalytic hydrogen evolution research.
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