Tandem catalysis for CO2 conversion to higher alcohols: A review

串联 催化作用 合成气 烯烃纤维 化学 生化工程 原材料 过程(计算) 组合化学 工艺工程 纳米技术 有机化学 计算机科学 材料科学 工程类 操作系统 复合材料
作者
Yiming He,Fabian Müller,Regina Palkovits,Feng Zeng,Chalachew Mebrahtu
出处
期刊:Applied Catalysis B-environmental [Elsevier]
卷期号:345: 123663-123663 被引量:19
标识
DOI:10.1016/j.apcatb.2023.123663
摘要

In recent years, due to the substantial emission of CO2, global warming has become more severe, and there is an urgent need to develop technologies to reduce greenhouse gas CO2 emissions. Converting CO2 into higher alcohols is a promising process, as it not only produces valuable chemicals but also utilizes CO2 as feedstock. Currently, most reported catalytic approaches are based on direct hydrogenation of CO2 to synthesize higher alcohols. However, the synthesis of higher alcohols involves multiple steps, requiring catalysts with multiple functional sites and their synergistic interactions are crucial. Nevertheless, controlling catalysts at the nanoscale poses challenges, hindering the design of efficient multi-site catalysts. An alternative approach worth considering is to perform a tandem of multiple well-established catalytic reactions (e.g., methanol synthesis, CO2-Fischer-Tropsch-Synthesis, RWGS, syngas conversion, olefin hydration, etc.) to indirectly achieve the conversion of CO2 into higher alcohols, instead of direct CO2 hydrogenation. Therefore, in this review, these alternative strategies of higher alcohols synthesis are discussed, and their potential is evaluated. First, thermodynamic analysis, the selective adjustment strategies, and the current challenges faced for direct CO2 hydrogenation are introduced. Then, physical integration of multiple catalysts as a feasible strategy to endow the catalyst with multifunctional properties is discussed. Subsequently, several feasible routes of CO2 conversion into higher alcohols and the advanced catalysts employed for each pathway are summarized. Finally, merits and limitations of the different approaches are provided, emphasizing the great potential the tandem reaction strategy holds for the efficient synthesis of higher alcohols by CO2 conversion.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
大幅提高文件上传限制,最高150M (2024-4-1)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
战斗大排排完成签到 ,获得积分10
2秒前
张子子发布了新的文献求助10
3秒前
3秒前
mochi发布了新的文献求助10
7秒前
i羽翼深蓝i完成签到,获得积分10
8秒前
科研科研完成签到 ,获得积分10
9秒前
小二郎应助maaicui采纳,获得10
11秒前
sixone完成签到,获得积分10
11秒前
13秒前
彭于晏应助圆仔采纳,获得10
14秒前
Sun_Chen发布了新的文献求助30
14秒前
16秒前
TearMarks完成签到 ,获得积分10
16秒前
憨憨完成签到,获得积分10
16秒前
DrLin完成签到,获得积分10
19秒前
盐汽水完成签到 ,获得积分10
20秒前
hubo完成签到,获得积分10
21秒前
21秒前
你帅你有理完成签到,获得积分10
22秒前
江子川发布了新的文献求助10
22秒前
22秒前
blush完成签到 ,获得积分10
23秒前
希望天下0贩的0应助沐雨采纳,获得10
24秒前
沈海完成签到,获得积分10
24秒前
sun2发布了新的文献求助10
25秒前
梓歆发布了新的文献求助10
26秒前
凶狠的绿兰完成签到,获得积分10
26秒前
27秒前
华仔应助饱满的醉山采纳,获得10
27秒前
pu完成签到 ,获得积分10
28秒前
HH完成签到,获得积分10
30秒前
小茹发布了新的文献求助10
30秒前
sun2完成签到,获得积分10
30秒前
李cy发布了新的文献求助10
31秒前
zhangruixue0519完成签到 ,获得积分10
32秒前
张子子完成签到,获得积分20
32秒前
江子川完成签到,获得积分10
35秒前
wang研通应助仁爱乐萱采纳,获得50
36秒前
39秒前
黎明的第一道曙光完成签到 ,获得积分10
39秒前
高分求助中
The Oxford Handbook of Social Cognition (Second Edition, 2024) 1050
Kinetics of the Esterification Between 2-[(4-hydroxybutoxy)carbonyl] Benzoic Acid with 1,4-Butanediol: Tetrabutyl Orthotitanate as Catalyst 1000
The Young builders of New china : the visit of the delegation of the WFDY to the Chinese People's Republic 1000
юрские динозавры восточного забайкалья 800
English Wealden Fossils 700
Chen Hansheng: China’s Last Romantic Revolutionary 500
Mantiden: Faszinierende Lauerjäger Faszinierende Lauerjäger 500
热门求助领域 (近24小时)
化学 医学 生物 材料科学 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 基因 遗传学 催化作用 物理化学 免疫学 量子力学 细胞生物学
热门帖子
关注 科研通微信公众号,转发送积分 3140431
求助须知:如何正确求助?哪些是违规求助? 2791320
关于积分的说明 7798479
捐赠科研通 2447661
什么是DOI,文献DOI怎么找? 1302008
科研通“疑难数据库(出版商)”最低求助积分说明 626359
版权声明 601194