Expedient Deaminative Phosphorylation and Sulfonylation of Benzylic Tertiary Amines Enabled by Difluorocarbene
二氟卡宾
化学
组合化学
有机化学
作者
Chengbo Li,Xiao‐Qi Yu,Jianke Su,Xinyuan Hu,Qingqing Xuan,Qiuling Song
出处
期刊：Organic chemistry frontiers [The Royal Society of Chemistry] 日期：2024-01-01
标识
DOI：10.1039/d4qo00412d
摘要
A deaminative functionalization of aliphatic tertiary amines via the cleavage of C(sp 3 )–N bonds under transition metal-free conditions was disclosed, which goes through S N 2 reaction with various phosphorus and sulfur nucleophiles.
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