Enhancement of SrSi2O2N2:Eu2+ phosphor by means of oxygen to nitrogen control

三斜晶系 荧光粉 光致发光 发光 分析化学(期刊) 晶格常数 材料科学 晶体结构 氮化硅 相(物质) 量子产额 矿物学 化学 结晶学 衍射 光学 荧光 冶金 光电子学 有机化学 物理 色谱法
作者
Sebastian Mahlik,Justyna Barzowska,Karol Szczodrowski,Natalia Majewska,M. Grinberg,D. Michalik,B. Adamczyk,Tomasz Pawlik,T. Rzychoń,Anna Adamczyk,M. Sopicka-Lizer
出处
期刊:Journal of Alloys and Compounds [Elsevier BV]
卷期号:884: 161047-161047 被引量:9
标识
DOI:10.1016/j.jallcom.2021.161047
摘要

In this study phosphor powders with the nominal composition of Sr0.98Eu0.02Si2O(5–1.5x)Nx (x in the range of 1.33–2.66) was successfully synthesized through the conventional solid-state reaction method. We carried out studies on the N3- and O2- ions effects on the structural and photoluminescent properties of the resultant oxonitridosilicates by varying nitrogen content in the initial mixture of materials. Discussion on the multicomposition effect on the luminescent properties is provided since the specimen with the bi-phase composition shows the highest quantum yield (QY) among the examined specimens. We found that luminescence peaked at 540 nm is related to Eu2+ located in the triclinic phase SrSi2O2N2. It is shown that QY of the single triclinic phase materials is relatively low. We related low QY to absorption of excitation light by uncontrolled defects. We found that the sample where the ratio of Si in silica to Si in silicon nitride is 0.5:1.5 has high QY equal to 0.68. This sample is a mixture of two phases: the triclinic phase SrSi2O2N2 and another crystal lattice, the most likely Sr3Si6O9N4. We can relate the parasite defects to the surface states in the triclinic lattice, which in the case of existence, the Sr3Si6O9N4 phase are removed.
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