催化作用
化学
溶剂
基质(水族馆)
锂(药物)
有机化学
蒸馏
摩尔比
减压蒸馏
加合物
氯化锂
氯化物
医学
海洋学
地质学
内分泌学
作者
Nobuhito Kurono,Masayo Yamaguchi,Ken Suzuki,Takeshi Ohkuma
摘要
LiCl acts as a highly effective catalyst for cyanosilylation of various aldehydes and ketones to the corresponding silylated cyanohydrins. The reaction proceeds smoothly with a substrate/catalyst molar ratio of 100-100,000 at 20-25 degrees C under solvent-free conditions. alpha,beta-Unsaturated aldehydes are completely converted to the 1,2-adducts. The cyanation products can be isolated by direct distillation of the reaction mixture.
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