材料科学
纳米复合材料
光催化
X射线光电子能谱
球磨机
化学工程
透射电子显微镜
尖晶石
甲基橙
扫描电子显微镜
高分辨率透射电子显微镜
核化学
纳米技术
复合材料
冶金
催化作用
化学
有机化学
工程类
作者
Alireza Mohammadi,V. Mahdikhah,S. Sheibani
标识
DOI:10.1016/j.optmat.2022.112716
摘要
In this paper, CuCrO2/CuCr2O4 nanocomposite powder was synthesized by a solid-state mechano-thermal reaction between Cu2O and Cr2O3 powder, and the effect of 20 h initial ball milling on various properties was studied. The improvement of photocatalytic activity through the modification of the structure was also studied. The results showed that ball milling before the heat treatment process has led to the formation of a nanocomposite of spinel CuCr2O4 and delafossite CuCrO2. According to the field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) results, after 20 h of ball milling, the microstructure became fine and homogeneous, and the powder with an average particle size of 174 ± 5 nm was observed. The X-Ray Photoelectron Spectroscopy (XPS) study shows the formation of CuCrO2/CuCr2O4 through the mechano-thermal process. The ball milling process narrowed the bandgap of the photocatalyst to 2.60 eV. The lower intensities of the nanocomposite photoluminescence (PL) peak indicated a lower electron-hole pair recombination rate. Also, the nanocomposite produces a current density of 1.77 times higher than the single-phase CuCrO2 sample. In methylene blue (MB) degradation, a favorable photocatalytic performance (85%) under visible light irradiation was obtained with the nanocomposite photocatalyst. the degradation of MB over both photocatalysts was approximately 50% higher than that of methyl orange (MO). After 3 runs of the photocatalytic test on the nanocomposite sample, no significant loss in the performance of the photocatalyst was observed.
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