Muscle-inspired anisotropic carboxymethyl cellulose-based double-network conductive hydrogels for flexible strain sensors

Conductive hydrogels are considered one of the most promising materials for preparing flexible sensors due to their flexible and extensible properties. However, conventional hydrogels' weak mechanical and isotropic properties are greatly limited in practical applications. Here, the internal structure of the hydrogel was regulated by pre-stretching synergistic ion crosslinking to construct a carboxymethyl cellulose-based double network-oriented hydrogel similar to muscle. The introduction of pre-stretching increased the tensile strength of the double-network hydrogel from 1.45 MPa to 4.32 MPa, and its light transmittance increased from 67.3 % to 84.5 %. In addition, the hydrogel's thermal stability and electrical conductivity were improved to a certain extent. Its good mechanical properties and conductive properties can be converted into stable electrical signal output during deformation. The carboxymethyl cellulose-based double network oriented hydrogels were further assembled as flexible substrates into flexible sensor devices. The hydrogel sensors can monitor simple joint movements as well as complex spatial movements, which makes them have potential application value in the research field of intelligent response electronic devices such as flexible wearables, intelligent strain sensing, and soft robots.