Copper and Cobalt Nanoparticles Enable Highly Stable and Fast Kinetics of Al–S Batteries

Abstract Aluminum–Sulfur (Al–S) batteries are regarded as promising energy storage devices due to their high energy‐to‐price ratios and safety. However, they suffer from clumsy S ↔ Al 2 S 3 reactions and short lifespans that limit their practical application. By combining the merits of adsorptive Cu, catalytic Co, and conductive N‐doped carbon matrix, the bimetals decorated N‐doped carbon (Cu 1 Co 1 @NC) enables smooth adsorption and conversion of polysulfides. Consequently, the S@Cu 1 Co 1 @NC exhibits excellent electrochemical performance (delivering a high capacity of 317.5 mAh g −1 after 320 cycles at 1.5 A g −1 ). Moreover, the Cu‐endowed strong Al affinity and robust 3D scaffold with Co‐enhanced conductivity can regulate Al 3+ depositing/stripping and successfully suppress Al dendrites. As a result, the Cu 1 Co 1 @NC displays negligible Al nucleation overpotential and provides ultra‐long lifespan (>10 000 h) and exceptional reversible (Coulombic efficiency = 99.8–99.9%) Al 3+ plating/stripping. Integrating all these advantages, a full Al–S cell constructed with Cu 1 Co 1 @NC as two‐in‐one hosts demonstrates excellent capacity retention with enhanced reversibility. This work provides insights into the design of promising Al–S batteries based on bifunctional CuCo bimetal and favorable 3D framework.