吸附
化学
水溶液
离子交换树脂
离子交换
腐植酸
傅里叶变换红外光谱
朗缪尔吸附模型
朗缪尔
有机质
水处理
离子
无机化学
化学工程
有机化学
废物管理
工程类
肥料
作者
Xingdi Ma,Yangxue Liu,Zhonglin Chen,Yingxu Gong,Binyuan Wang,Jimin Shen,Jing Kang,Pengwei Yan,Shengxin Zhao
标识
DOI:10.1080/10934529.2024.2433361
摘要
In this study, humic acid was used as a model pollutant to investigate the removal effect of a macroporous weakly alkaline anion exchange resin D301 on natural organic matter (NOM) in water. 3D fluorescence spectroscopy, UV - visible spectrophotometry and Fourier transform infrared (FTIR) spectroscopy were employed to analyze changes in the physical and chemical properties of humic acid solution and natural water samples before and after resin adsorption. The results showed that using humic acid as a model pollutant to simulate NOM in water is feasible. Through kinetic and thermodynamic analysis, ion exchange was identified as the dominant mechanism for the adsorption of organic matter by D301 resin. According to the Langmuir adsorption isotherm, the maximum adsorption capacity of the resin was 37.78 mg/g. The adsorption of NOM by the exchange resin effectively conformed to the Thomas, Yoon - Nelson, and BDST models, offering a reliable basis for practical application prediction. Using sodium chloride solution as the regeneration solution for D301 resin column, after several regenerations, the adsorption efficiency of the resin did not change significantly, which indicated that the anion - exchange resin can be used as an efficient and reusable adsorbent for the removal of NOM from water.
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