材料科学
假电容
阳极
阴极
碳纤维
电解质
电容
电导率
化学工程
超级电容器
兴奋剂
纳米技术
离子
光电子学
复合材料
电极
复合数
有机化学
物理化学
工程类
化学
作者
Sahar Hemmati,Ge Li,Xiaolei Wang,Yuan‐Li Ding,Yu Pei,Aiping Yu,Zhongwei Chen
出处
期刊:Nano Energy
[Elsevier]
日期:2018-10-25
卷期号:56: 118-126
被引量:112
标识
DOI:10.1016/j.nanoen.2018.10.048
摘要
Herein, a unique nitrogen-doped T-Nb2O5/tubular carbon hybrid structure in which T-Nb2O5 nanoparticles are homogeneously embedded in an in-situ formed nitrogen-doped microtubular carbon is synthesized, utilizing a facile and innovative synthesis strategy. This structure addresses the poor electron conductivity and rate capability that hinder T-Nb2O5's promise as an anode for Li-ion devices. Such a distinctive structure possesses a robust framework that has ultrasmall active nanocomponents encapsulated in highly conductive carbon scaffold with hollow interior and abundant voids, enabling fast electron/ion transport and electrolyte penetration. Moreover, nitrogen-doping not only ameliorates the electronic conductivity of the heterostructure, but also induces pseudocapacitance mechanism. When evaluated in a half-cell, the as-prepared material delivers a specific capacitance of 370 F g−1 at 0.1 A g−1 within 1–3 V vs. Li/Li+ and excellent cyclability over 1100 cycles. A high energy density of 86.6 W h kg−1 and high power density of 6.09 kW kg−1 are realized. Additionally, a capacitance retention as high as 81% after 3500 cycles is achieved in an Li-ion Capacitor (LIC) with activated carbon as the cathode and nitrogen-doped T-Nb2O5/tubular carbon as the anode.
科研通智能强力驱动
Strongly Powered by AbleSci AI