纳米团簇
铜
锆
催化作用
反应性(心理学)
材料科学
制作
选择性
金属有机骨架
化学工程
纳米技术
纳米颗粒
化学
冶金
吸附
有机化学
病理
替代医学
工程类
医学
作者
Shan Dai,T. Kajiwara,Miyuki Ikeda,Ignacio Romero‐Muñiz,G. Patriarche,Ana E. Platero‐Prats,Alexandré Vimont,Marco Daturi,Antoine Tissot,Qiang Xu,Christian Serre
标识
DOI:10.1002/anie.202211848
摘要
Abstract Encapsulating ultrasmall Cu nanoparticles inside Zr‐MOFs to form core–shell architecture is very challenging but of interest for CO 2 reduction. We report for the first time the incorporation of ultrasmall Cu NCs into a series of benchmark Zr‐MOFs, without Cu NCs aggregation, via a scalable room temperature fabrication approach. The Cu NCs@MOFs core–shell composites show much enhanced reactivity in comparison to the Cu NCs confined in the pore of MOFs, regardless of their very similar intrinsic properties at the atomic level. Moreover, introducing polar groups on the MOF structure can further improve both the catalytic reactivity and selectivity. Mechanistic investigation reveals that the Cu I sites located at the interface between Cu NCs and support serve as the active sites and efficiently catalyze CO 2 photoreduction. This synergetic effect may pave the way for the design of low‐cost and efficient catalysts for CO 2 photoreduction into high‐value chemical feedstock.
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