Design strategies and mechanisms of g–C3N4–based photoanodes for photoelectrocatalytic degradation of organic pollutants in water

Emerging photoelectrocatalytic (PEC) systems integrate the advantages of photocatalysis and electrocatalysis and are considered as a promising technology for solving the global organic pollution problem in water environments. Among the photoelectrocatalytic materials applied for organic pollutant degradation, graphitic carbon nitride (CN) has the combined advantages of environmental compatibility, stability, low cost, and visible light response. However, pristine CN has disadvantages such as low specific surface area, low electrical conductivity, and high charge complexation rate, and how to improve the degradation efficiency of PEC reaction and the mineralization rate of organic matter is the main problem faced in this field. Therefore, this paper reviews the progress of various functionalized CN used for PEC reaction in recent years, and the degradation efficiency of these CN-based materials is critically evaluated. First, the basic principles of PEC degradation of organic pollutants are outlined. Then, engineering strategies to enhance the PEC activity of CN (including morphology control, elemental doping, and heterojunction construction) are focused on, and the structure-activity relationships between these engineering strategies and PEC activity are discussed. In addition, the important role of influencing factors on the PEC system is summarized in terms of mechanism, to provide guidance for the subsequent research. Finally, suggestions and perspectives are provided for the preparation of efficient and stable CN-based photoelectrocatalysts for practical wastewater treatment applications.