Preparation of Pressure‐Resistant and Mechanically Durable Superhydrophobic Coatings via Non‐Solvent Induced Phase Separation for Anti‐Icing

Abstract Inspired by the lotus leaf effect, superhydrophobic coatings have significant potential in various fields, However, their poor pressure resistance, weak mechanical durability, and complex preparation processes severely limit practical applications. Here, a method for preparing pressure‐resistant and durable superhydrophobic coatings by simply spray‐coating a phase separation suspension containing fluorinated silica nanoparticles and polyolefin adhesive onto substrates is introduced, which forms superhydrophobic coatings with a porous and hierarchical micro‐/nanostructure. The resulting superhydrophobic coatings exhibit outstanding pressure resistance, maintaining a Cassie‐Baxte state after 18 days of submersion in 1 m of water. Furthermore, the coatings demonstrate remarkable mechanical durability, withstanding 200 cycles of Taber abrasion, 100 cycles of tape‐peeling, and 750 g of sand abrasion. The coatings also show excellent chemical stability, enduring long‐term immersion in corrosive liquids and 120 d of outdoor exposure. Additionally, the coatings display excellent anti‐icing properties and can be applied to various substrate surfaces. This approach improves on the limitations of conventional superhydrophobic coatings and accelerates the application of superhydrophobic coatings in real‐world environments.