结晶
傅里叶变换红外光谱
溶剂
扫描电子显微镜
乙醚
粒径
Crystal(编程语言)
升华(心理学)
粒度分布
杂质
化学
材料科学
二甲基甲酰胺
分析化学(期刊)
结晶学
化学工程
色谱法
有机化学
物理化学
复合材料
心理治疗师
程序设计语言
工程类
计算机科学
心理学
作者
Jianxin Chen,Fengjiang Chen,Jian Han,Min Su,Kaili Liu,Yinhui Li,Qing Wu
标识
DOI:10.1002/ceat.201900519
摘要
Abstract The purification of 4,4′‐diaminodiphenyl ether (ODA) was investigated. ODA, which contained impurities, was sublimated and anti‐solvent (ethanol)‐crystallized in N ‐dimethylformamide (DMF). Fourier transform infrared (FTIR) results revealed that the sublimated crystal was basically identical with the pure ODA sample. The influence of different amounts of ethanol on particle size distribution was analyzed during anti‐solvent crystallization. The morphology of the ODA crystal was examined by scanning electron microscopy (SEM). The color of the sample enhanced from a brown powder to a colorless granular crystal. The purity of the sample could be increased from about 30 % to 87 %. With the operations of sublimation and anti‐solvent crystallization, the purity, crystal morphology, and particle size distribution of ODA were significantly improved.
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