比纳普
钌
不对称氢化
催化作用
介孔材料
共聚物
对映选择合成
聚合物
化学
组合化学
高分子化学
配体(生物化学)
有机化学
生物化学
受体
作者
Qi Sun,Xiangju Meng,Xiao Liu,Xiaoming Zhang,Yan Yang,Qihua Yang,Feng‐Shou Xiao
摘要
We report here a successful preparation of a heterogeneous chiral catalyst from copolymerization of mesoporous cross-linked polymer with chiral BINAP ligands, followed by coordination of the BINAP with a ruthenium species, which exhibits high activity, excellent enantioselectivity, and extraordinary recyclability in asymmetric hydrogenation.
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