阳极
介孔材料
材料科学
多孔性
锂(药物)
纳米颗粒
化学工程
粒子(生态学)
模板方法模式
粒径
纳米技术
电极
化学
复合材料
催化作用
物理化学
有机化学
医学
海洋学
地质学
工程类
内分泌学
作者
Xiaodong Xu,Ruiguo Cao,Sookyung Jeong,Jaephil Cho
出处
期刊:Nano Letters
[American Chemical Society]
日期:2012-08-12
卷期号:12 (9): 4988-4991
被引量:885
摘要
Spindle-like porous α-Fe(2)O(3) was prepared from an iron-based metal organic framework (MOF) template. When tested as anode material for lithium batteries (LBs), this spindle-like porous α-Fe(2)O(3) shows greatly enhanced performance of Li storage. The particle with a length and width of ∼0.8 and ∼0.4 μm, respectively, was composed of clustered Fe(2)O(3) nanoparticles with sizes of <20 nm. The capacity of the porous α-Fe(2)O(3) retained 911 mAh g(-1) after 50 cycles at a rate of 0.2 C. Even when cycled at 10 C, comparable capacity of 424 mAh g(-1) could be achieved.
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