石墨烯
检出限
材料科学
纳米棒
罗丹明B
重复性
复合数
电化学
电化学气体传感器
氧化物
再现性
电极
核化学
分析化学(期刊)
纳米技术
化学
色谱法
复合材料
冶金
有机化学
催化作用
物理化学
光催化
作者
Quanguo He,Jun Liu,Yonghui Xia,Du Tuo,Peihong Deng,Yaling Tian,Yiyong Wu,Guangli Li,Dongchu Chen
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2019-01-01
卷期号:166 (10): B805-B813
被引量:60
摘要
A facile voltammetric sensor based on MnO2 nanorods/electro-reduced graphene oxide composite modified glassy carbon electrode (MnO2NRs-ERGO/GCE) was proposed for the detection of Rhodamine B (RhB). The MnO2NRs-ERGO/GCE was fabricated by a facile drop-casting approach followed by a potentiostatic reduction technique. A well-shaped oxidation peak of RhB was observed at the MnO2NRs-ERGO/GCE, and the response peak current was 17-fold and 2-fold higher than that of bare GCE and ERGO/GCE respectively, attributing to the synergistic electrocatalytic effect from ERGO sheets and MnO2NRs. Under the optimal analytical conditions, the response peak currents linearly increased with the RhB concentrations varying from 0.02 μM to 1.0 μM and from 1.0 μM to 20 μM. The limit of detection (LOD, S/N = 3) was 6.0 nM. Furthermore, the MnO2NRs-ERGO/GCE showed good selectivity, repeatability, reproducibility and stability. Finally, the MnO2NRs-ERGO/GCE was successfully employed to detect RhB in different commercial chili-containing foodstuffs, and the results were in good accordance with the values that detected by high-performance liquid chromatography. Combining with low cost and portable electrochemical apparatus, the proposed sensor is especially suitable for the in-situ detection of RhB in actual food samples.
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