Controllable Synthesis of Metal–Organic Frameworks: From MOF Nanorods to Oriented MOF Membranes

Advanced MaterialsVolume 22, Issue 30 p. 3322-3326 Communication Controllable Synthesis of Metal–Organic Frameworks: From MOF Nanorods to Oriented MOF Membranes Yan-Shuo Li, Corresponding Author Yan-Shuo Li [email protected] Institute of Physical Chemistry and Electrochemistry, and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz University Hannover, Callinstrasse 3A, 30167 Hannover (Germany) State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhong-Shan Road 457, 116023 Dalian (P. R. China)Institute of Physical Chemistry and Electrochemistry, and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz University Hannover, Callinstrasse 3A, 30167 Hannover (Germany).Search for more papers by this authorHelge Bux, Helge Bux Institute of Physical Chemistry and Electrochemistry, and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz University Hannover, Callinstrasse 3A, 30167 Hannover (Germany)Search for more papers by this authorArmin Feldhoff, Corresponding Author Armin Feldhoff [email protected] Institute of Physical Chemistry and Electrochemistry, and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz University Hannover, Callinstrasse 3A, 30167 Hannover (Germany)Institute of Physical Chemistry and Electrochemistry, and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz University Hannover, Callinstrasse 3A, 30167 Hannover (Germany).Search for more papers by this authorGuo-Ling Li, Guo-Ling Li State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhong-Shan Road 457, 116023 Dalian (P. R. China)Search for more papers by this authorWei-Shen Yang, Wei-Shen Yang State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhong-Shan Road 457, 116023 Dalian (P. R. China)Search for more papers by this authorJürgen Caro, Jürgen Caro Institute of Physical Chemistry and Electrochemistry, and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz University Hannover, Callinstrasse 3A, 30167 Hannover (Germany)Search for more papers by this author Yan-Shuo Li, Corresponding Author Yan-Shuo Li [email protected] Institute of Physical Chemistry and Electrochemistry, and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz University Hannover, Callinstrasse 3A, 30167 Hannover (Germany) State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhong-Shan Road 457, 116023 Dalian (P. R. China)Institute of Physical Chemistry and Electrochemistry, and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz University Hannover, Callinstrasse 3A, 30167 Hannover (Germany).Search for more papers by this authorHelge Bux, Helge Bux Institute of Physical Chemistry and Electrochemistry, and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz University Hannover, Callinstrasse 3A, 30167 Hannover (Germany)Search for more papers by this authorArmin Feldhoff, Corresponding Author Armin Feldhoff [email protected] Institute of Physical Chemistry and Electrochemistry, and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz University Hannover, Callinstrasse 3A, 30167 Hannover (Germany)Institute of Physical Chemistry and Electrochemistry, and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz University Hannover, Callinstrasse 3A, 30167 Hannover (Germany).Search for more papers by this authorGuo-Ling Li, Guo-Ling Li State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhong-Shan Road 457, 116023 Dalian (P. R. China)Search for more papers by this authorWei-Shen Yang, Wei-Shen Yang State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhong-Shan Road 457, 116023 Dalian (P. R. China)Search for more papers by this authorJürgen Caro, Jürgen Caro Institute of Physical Chemistry and Electrochemistry, and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz University Hannover, Callinstrasse 3A, 30167 Hannover (Germany)Search for more papers by this author First published: 03 August 2010 https://doi.org/10.1002/adma.201000857Citations: 362Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Tailoring of the crystal size and morphology of metal–organic framework (MOF) materials and manipulation of MOF films is possible by the solvothermal synthesis route introduced here. A c-out-of-plane ZIF-7 membrane (see figure) is obtained through evolutionary selection in a van der Drift–type growth originating from randomly oriented seed layers. Highly oriented MOF thin films are important as molecular sieve membranes. Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description adma_201000857_sm_supplfigs.pdf211.9 KB supplfigs Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 a) S. Kitagawa, R. Kitaura, S. Noro, Angew. Chem. Int. Ed. 2004, 43, 2334; b) M. Yaghi, M. O'Keeffe, N. W. Ockwig, H. K. Chae, M. Eddaoudi, J. Kim, Nature 2003, 423, 705; c) G. Feréy, Chem. Soc. Rev. 2008, 37, 191; d) S. L. James, Chem. Soc. Rev. 2003, 32, 276; e) J.-R. Li, R. J. Kuppler, H.-C. Zhou, Chem. Soc. Rev. 2009, 38, 1477; f) J. Lee, O. K. Farha, J. Roberts, K. A. Scheidt, S. T. Nguyen, J. T. Hupp, Chem. Soc. Rev. 2009, 38, 1450; g) X. D. Chen, C. Q. Wan, H. H. Y. Sung, I. D. Williams, T. C. W. Mak, Chem. Eur. J. 2009, 15, 6518; h) J. A. Hurd, R. Vaidhyanathan, V. Thangadurai, C. I. Ratcliffe, I. L. Moudrakovski, G. K. H. Shimizu, Nat. Chem. 2009, 1, 705. 2 a) D. Zacher, O. Shekhah, C. Wöll, R. A. Fischer, Chem. Soc. Rev. 2009, 38, 1418; b) M. Arnold, P. Kortunov, D. J. Jones, Y. Nedellec, J. Kärger, J. Caro, Eur. J. Inorg. Chem. 2007, 1, 60; c) Y. Yoo, H. K. Jeong, Chem. Commun. 2008, 2441; d) J. Gascon, S. Aguado, F. Kapteijn, Microporous Mesoporous Mater. 2008, 113, 132; e) Y. Liu, Z. Ng, E. A. Khan, H. K. Jeong, C. Ching, Z. P. Lai, Microporous Mesoporous Mater. 2009, 118, 296; f) Y. Yoo, Z.-P. Lai, H. K. Jeong, Microporous Mesoporous Mater. 2009, 123, 100; g) H. Guo, G. Zhu, I. J. Hewitt, S. L. Qiu, J. Am. Chem. Soc. 2009, 131, 1646; h) R. Ranjan, M. Tsapatsis, Chem. Mater. 2009, 21, 4920; i) H. Bux, F. Y. Liang, Y. S. Li, J. Cravillon, M. Wiebcke, J. Caro, J. Am. Chem. Soc. 2009, 131, 16000; j) Y. S. Li, F. Y. Liang, H. Bux, A. Feldhoff, W. S. Yang, J. Caro, Angew. Chem. Int. Ed. 2010, 49, 548; k) Y. S. Li, F. Y. Liang, H. Bux, W. S. Yang, J. Caro, J. Membr. Sci. 2010, 354, 48. 3 S. Hemes, T. Witte, T. Hitov, D. Zacher, S. Bahnmueller, G. Langstein, K. Huber, R. A. Fischer, J. Am. Chem. Soc. 2009, 126, 5324. 4 T. Tsuruoka, S. Furukawa, Y. Takashima, K. Yoshida, S. Isoda, S. Kitagawa, Angew. Chem. Int. Ed. 2009, 48, 4739. 5 Z. Ni, R. I. Masel, J. Am. Chem. Soc. 2006, 128, 12394. 6 Z. Q. Li, L. G. Qiu, T. Xu, Y. Wu, W. Wang, Z. Y. Wu, X. Jiang, Mater. Lett. 2009, 63, 78. 7 K. M. L. Taylor, W. J. Rieter, W. B. Lin, J. Am. Chem. Soc. 2008, 130, 14358. 8 a) E. Biemmi, C. Scherb, T. Bein, J. Am. Chem. Soc. 2007, 129, 8054; b) S. Hermes, F. Schröder, R. Chelmowski, C. Wöll, R. A. Fischer, J. Am. Chem. Soc. 2005, 127, 13744. 9 a) O. Shekhah, H. Wang, S. Kowarik, F. Schreiber, M. Paulus, M. Tolan, C. Sternemann, F. Evers, D. Zacher, R. A. Fischer, C. Wöll, J. Am. Chem. Soc 2007, 129, 15118; b) O. Shekhah, H. Wang, T. Strunskus, P. Cyganik, D. Zacher, R. A. Fischer, C. Wöll, Langmuir 2006, 23, 7740. 10 a) X. C. Huang, J. P. Zhang, X. M. Chen, Chin. Sci. Bull. 2003, 48, 1531; b) K. S. Park, Z. Ni, A. P. Côté, J. Y. Choi, R. Huang, F. J. Uribe-Romo, H. K. Chae, M. O'Keeffe, O. M. Yaghi, Proc. Natl. Acad. Sci. USA 2006, 103, 10186. 11 a) Z. P. Lai, G. Bonilla, I. Diaz, J. G. Nery, K. Sujaoti, M. A. Amat, E. Kokkoli, O. Terasaki, R. W. Thompson, M. Tsapatsis, D. G. Vlachos, Science 2003, 300, 456; b) M. A. Snyder, M. Tsapatsis, Angew. Chem. Int. Ed. 2007, 46, 7560. 12 A. Van Der Drift, Philips Res. Rep. 1967, 22, 267. 13 P. Hartman, W. Perdok, Acta Crystallogr. 1955, 8, 521. 14 R. G. Pearson, J. Am. Chem. Soc. 1963, 85, 3533. 15 a) M. A. Withersby, A. J. Blake, N. R. Champness, P. Hubberstey, W. S. Li, M. Schröder, Angew. Chem., Int. Ed. 1997, 36, 2327; b) N. R. Brooks, A. J. Blake, N. R. Champness, J. W. Cunningham, P. Hubberstey, S. J. Teat, C. Wilson, M. Schröder, J. Chem. Soc., Dalton Trans. 2001, 2530. 16 A. J. Bons, P. D. Bons, Microporous Mesoporous Mater. 2003, 62, 9. 17 a) D. A. Newsome, D. S. Sholl, J. Phys. Chem. B 2005, 109, 7237; b) A. Feldhoff, J. Caro, H. Jobic, J. Ollivier, C. B. Krause, P. Galvosas, J. Kärger, ChemPhysChem 2009, 10, 2429. 18 a) H. J. Lee, W. Cho, S. Jung, M. Oh, Adv. Mater. 2008, 21, 674; b) T. Tsuruoka, S. Furukawa, Y. Takashima, K. Yoshida, S. Isoda, S. Kitagawa, Angew. Chem. Int. Ed. 2009, 48, 4739. Citing Literature Volume22, Issue30August 10, 2010Pages 3322-3326 ReferencesRelatedInformation