化学
电解
电化学
表面改性
硫脲
组合化学
碘化物
石墨
有机化学
电极
物理化学
电解质
作者
Pei Li,Shangfeng Yang,Zilin Fang,Haoran Cui,Sen Liang,Hongyu Tian,Baoguo Sun,Cheng‐Chu Zeng
标识
DOI:10.1016/j.jece.2022.107487
摘要
An efficient one-pot electrochemical protocol for the synthesis of 2-aminothiazoles has been described from electrolysis of ketones with thioureas mediated by iodide ion. The electrochemical synthesis was conducted in an undivided cell equipped with graphite plates electrodes under constant current conditions. A diversity of aromatic and aliphatic ketones was suitable for the reaction, yielding the corresponding 2-aminothiazoles in satisfactory yields. Mechanistically, the in-situ generated α-iodoketone was proposed to be a key active species.
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