环加成
分子内力
异恶唑
化学
催化作用
烯烃
高价分子
产量(工程)
炔烃
组合化学
芳基
氧化磷酸化
药物化学
有机化学
碘
烷基
生物化学
材料科学
冶金
作者
Irina Mironova,Valentine G. Nenajdenko,Pavel S. Postnikov,Akinori Saito,Mekhman S. Yusubov,Akira Yoshimura
出处
期刊:Molecules
[MDPI AG]
日期:2022-06-16
卷期号:27 (12): 3860-3860
被引量:1
标识
DOI:10.3390/molecules27123860
摘要
The intramolecular oxidative cycloaddition reaction of alkyne- or alkene-tethered aldoximes was catalyzed efficiently by hypervalent iodine(III) species to afford the corresponding polycyclic isoxazole derivatives in up to a 94% yield. The structure of the prepared products was confirmed by various methods, including X-ray crystallography. Mechanistic study demonstrated the crucial role of hydroxy(aryl)iodonium tosylate as a precatalyst, which is generated from 2-iodobenzoic acid and m-chloroperoxybenzoic acid in the presence of a catalytic amount of p-toluenesulfonic acid.
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