The development of Perovskite Solar Cells (PSCs) on flexible substrates marks a significant advancement in thin-film photovoltaic technology. However, current state-of-the-art research predominantly utilizes Poly(ethylene terephthalate) (PET) substrate, which limits the deployment to less challenging environments. To address this limitation, we explore the fabrication of inverted PSCs on colorless polyimide (CPI) substrates that can withstand harsh environmental conditions. We employed a sequential sputtering technique to deposit indium tin oxide (bottom electrode) and nickel oxide (hole transport layer) as a base stack for the perovskite. This base layer was further enhanced by incorporating MeO-2PACz into the hole transport bilayer, significantly improving the NiO