三元运算
光催化
甲醇
异质结
光电流
可见光谱
光电子学
吸附
材料科学
电化学
半导体
光化学
纳米复合材料
金属
化学
化学工程
纳米技术
电极
有机化学
催化作用
计算机科学
物理化学
工程类
程序设计语言
冶金
作者
Radhapada Manna,Guruprasad Bhattacharya,Puspendu Sardar,Shubham Raj,Anvi Jain,Amar Nath Samanta
标识
DOI:10.1016/j.ces.2024.119811
摘要
The photocatalytic CO2 reduction reaction using various semiconductors is exceedingly difficult due to the recombination of photo-exited electron-hole (e−, h+), inefficient irradiated light utilization, and lower adsorption capacity of CO2. An efficient design of the photocatalyst system is required to address this issue. The metal–organic frameworks (MOFs), particularly NH2-MIL-101(Fe) (NML-101(Fe)), have demonstrated exceptional efficiency in CO2 adsorption, and reduction because of its large surface area, efficient charge separation capacity, and ligand-to-metal charge transfer effect (LMCT). The synergistic effect of semiconductors CdS, g-C3N4 (GCN), and metal–organic framework on efficient photocatalytic CO2 conversion to CH3OH was investigated here. The successful synthesis and design of a dual Z-scheme NML-101(Fe)/CdS/GCN (NMCG(X)) ternary hetero-nanostructured system (THS) was demonstrated, in which CdS nanoparticles and NML-101(Fe) are deposited on the surface of GCN to form a dual Z-scheme mechanism with excellent photocatalytic performance. After 8 h of visible light irradiation, NMCG8 nanocomposites containing 37.5 % GCN, 25 % CdS, and 37.5 % NML-101(Fe) exhibit 1.53 times higher methanol production (53.89 µmolg−1) than pure NML-101(Fe) (35.11 µmolg−1). The efficient reduction of CO2 was largely attributed to the systematic transportation of photo-exited e− and h+ mediated by the dual Z-scheme mechanism, as demonstrated by PL spectra, electrochemical impedance spectra (EIS) studies, and Transient photocurrent response testing.
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