Traffic congestion has emerged as a primary obstacle to sustainable urban development and the livability of life. Seven super-large cities in China were the study area of this paper as the problem tends to be more severe in larger cities. First, frequently congested road segments were defined based on real-time traffic condition data from online maps. Then, the spatiotemporal characteristics of these road segments were explored. Finally, mitigation measures and ways to ease traffic congestion in big cities were discussed against the background of rapid urbanization. The results demonstrate that the proportion of frequently congested road segments takes up between 1.8% and 9.87% of China’s super-large cities. There is a positive correlation between the overall operational efficiency of the urban road network and the ratio of frequently congested road segments. Temporally, commuting patterns during the morning and evening are displayed by these road segments. Spatially, they also demonstrate significant clustering characteristics. The proportion of frequently congested road segments caused by the lack of alternative routes is about 20% in the six cities studied. The data for Chongqing is even higher at 42.94%. Therefore, congestion caused by the lack of alternative routes may be underestimated by existing research. This work could provide theoretical support for transportation planning and management. As cities continue to expand and urbanization accelerates, the significance of this research will increase.