Effects of external pressure on the performance and ageing of single-layer lithium-ion pouch cells

电极 老化 电池(电) 石墨 材料科学 锂(药物) 内阻 分析化学(期刊) 复合材料 化学 热力学 医学 色谱法 功率(物理) 遗传学 物理 物理化学 生物 内分泌学
作者
Abdilbari Shifa Mussa,Matilda Klett,Göran Lindbergh,Rakel Wreland Lindström
出处
期刊:Journal of Power Sources [Elsevier BV]
卷期号:385: 18-26 被引量:153
标识
DOI:10.1016/j.jpowsour.2018.03.020
摘要

The effects of external compression on the performance and ageing of NMC(1/3)/Graphite single-layer Li-ion pouch cells are investigated using a spring-loaded fixture. The influence of pressure (0.66, 0.99, 1.32, and 1.98 MPa) on impedance is characterized in fresh cells that are subsequently cycled at the given pressure levels. The aged cells are analyzed for capacity fade and impedance rise at the cell and electrode level. The effect of pressure distribution that may occur in large-format cells or in a battery pack is simulated using parallel connected cells. The results show that the kinetic and mass transport resistance increases with pressure in a fresh cell. An optimum pressure around 1.3 MPa is shown to be beneficial to reduce cyclable-lithium loss during cycling. The minor active mass losses observed in the electrodes are independent of the ageing pressure, whereas ageing pressure affects the charge transfer resistance of both NMC and graphite electrodes and the ohmic resistance of the cell. Pressure distribution induces current distribution but the enhanced current throughput at lower pressures cell does not accelerate its ageing. Conclusions from this work can explain some of the discrepancies in non-uniform ageing reported in the literature and indicate coupling between electrochemistry and mechanics.
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