热力学
粘度
材料科学
悬浮
吉布斯自由能
焓
液体粘度的温度依赖性
阿累尼乌斯方程
还原粘度
相对粘度
体积热力学
活化能
化学
物理化学
物理
量子力学
磁铁
作者
Manabu Watanabe,Chihiro Koyama,Yūki Watanabe,Takehiko Ishikawa
标识
DOI:10.1016/j.ijheatmasstransfer.2022.123435
摘要
Density and viscosity of Ni–Ti melts were measured under high-vacuum conditions using an electrostatic levitation technique. The density of Ni–Ti melts can be expressed as a linear function of temperature. The variation of viscosity of Ni–Ti melts with temperature can be reproduced by an Arrhenius function. The excess volume was obtained from the density results and is discussed using the thermodynamic functions of enthalpy of mixing and excess Gibbs energy. Viscosity shows a positive deviation from linear additivity. From comparison with theoretical models, the viscosity is roughly reproduced by Kozlov's model. The viscosity of Ni–Ti melts is possibly influenced by formation of clusters, which form based on congruently melting compounds.
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