Realizing Unassisted Photo‐Charging of Zinc–Air Batteries by Anisotropic Charge Separation in Photoelectrodes

Solar rechargeable zinc-air battery is a promising approach for capturing and storing intermittent solar energy through photoelectrochemical reactions. However, unassisted photo-charging of zinc-air batteries is challenging due to suboptimal carrier accumulation on photoelectrodes, resulting in sluggish reaction kinetics. Here, unassisted photo-charging of zinc-air battery is achieved by investigating anisotropic photogenerated charge separation on a series of representative semiconductors (ZnIn₂ S₄ , TiO₂ , and In₂ O₃ ), among which the exceptional anisotropic charge separation on a ZnIn₂ S₄ photoelectrode is revealed based on anisotropic charge diffusion capabilities. The charge separation is facet-dependent, which is observed using Kelvin probe force microscopy, verifying a cause-and-effect relationship between the photo-charge accumulation on photoelectrodes and their photo-charging performance in zinc-air batteries. This work achieves an unassisted photo-charging current density of 1.9 mA cm^-2 with a light-to-chemical energy conversion efficiency of 1.45%, highlighting the importance of anisotropic semiconductors for unassisted photo-charging of zinc-air batteries via efficient photogenerated charge separation.