Constructing Nitrogen‐Coordinated Single Atom Catalysts via Bond‐Plucking Strategy for Oxidation of Benzene

Single-atom catalysts (SACs) with nitrogen-coordinated active centers feature unique electronic and geometric structures and thus show high catalytic activity for various industrial reactions. Searching for operable synthesis protocols to accurately devise SACs is vital but remains challenging because commonly used high-temperature pyrolysis always causes unpredictable structural changes and inhomogeneous single-atom sites. Herein, a mild bond-plucking strategy is reported to construct atomically dispersed Cu supported on graphene-liked C