Inverse micellar phases of phospholipids and glycolipids

溶致性 化学 相(物质) 反向 胶束 结晶学 水溶液 有机化学 液晶 几何学 数学
作者
John M. Seddon,J.L. Robins,T. Gulik‐Krzywicki,Hervé Delacroix
出处
期刊:Physical Chemistry Chemical Physics [Royal Society of Chemistry]
卷期号:2 (20): 4485-4493 被引量:143
标识
DOI:10.1039/b004916f
摘要

We here review the current knowledge of lyotropic liquid-crystalline phases having structures based upon periodic three-dimensional packings of discrete inverse micellar aggregates. These have been shown during the last decade to be rather common in lipid systems, particularly in lipid mixtures. The most frequently observed such structure is a cubic phase of crystallographic spacegroup Fd3m. We have previously determined the structure of this inverse micellar cubic phase, both by X-ray diffraction (V. Luzzati, R. Vargas, A. Gulik, P. Mariani, J. M. Seddon and E. Rivas, Biochemistry, 1992, 31, 279) and by freeze fracture electron microscopy (FFEM) (H. Delacroix, T. Gulik-Krzywicki and J. M. Seddon, J. Mol. Biol., 1996, 258, 88), and have determined the effect of pressure on its stability (P. M. Duesing, J. M. Seddon, R. H. Templer and D. A. Mannock, Langmuir, 1997, 13, 265). We have measured the limiting hydration of the Fd3m phase in a number of lipid systems. We have found that electrical conductivity measurements can offer a simple way of distinguishing bicontinuous from discontinuous (inverse micellar) phases. We have also discovered a new optically-isotropic phase in a few lipid systems, at lower hydrations than the Fd3m cubic phase. The X-ray diffraction pattern does not appear to index as cubic, and we assume that this phase consists of a non-cubic complex 3-D packing of inverse micelles. It gives rise to three different fracture planes by FFEM, one of which is identical to the [111] fracture plane of the Fd3m cubic phase, with two different sub-domains with alternating aspects along the [111] direction being present. This implies that the two inverse micellar phases may be related by a restacking transition of planes normal to the cubic [111] direction, analogous to the fcc–hcp restacking transition of hard spheres.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
PDF的下载单位、IP信息已删除 (2025-6-4)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
一路芬芳完成签到,获得积分20
刚刚
2秒前
一一一应助songvv采纳,获得10
2秒前
2秒前
SciKid524完成签到 ,获得积分10
4秒前
科研通AI2S应助hhh采纳,获得10
4秒前
QWE完成签到,获得积分10
4秒前
赛赛完成签到 ,获得积分10
6秒前
tinydog完成签到,获得积分10
8秒前
长情琦完成签到,获得积分10
8秒前
Mercury完成签到 ,获得积分10
10秒前
zx完成签到 ,获得积分10
11秒前
Dearjw1655完成签到,获得积分10
12秒前
123完成签到 ,获得积分10
12秒前
圆圆完成签到 ,获得积分10
13秒前
17秒前
哭泣笑柳发布了新的文献求助10
18秒前
张宁波完成签到,获得积分10
18秒前
OeO完成签到 ,获得积分10
18秒前
macboy完成签到,获得积分10
20秒前
biubiu完成签到,获得积分10
21秒前
咸鱼之王完成签到,获得积分10
22秒前
比比谁的速度快给ljm的求助进行了留言
22秒前
Can完成签到,获得积分10
23秒前
hhh完成签到,获得积分10
23秒前
qqq发布了新的文献求助10
23秒前
E0702完成签到,获得积分10
23秒前
25秒前
lin完成签到 ,获得积分20
26秒前
乐乐应助科研通管家采纳,获得10
29秒前
29秒前
29秒前
yi完成签到,获得积分10
30秒前
biofresh发布了新的文献求助30
30秒前
一路芬芳发布了新的文献求助10
32秒前
重要小兔子完成签到,获得积分10
33秒前
王大锤完成签到,获得积分10
34秒前
乌兰巴托没有海完成签到,获得积分10
37秒前
40秒前
lin关注了科研通微信公众号
41秒前
高分求助中
【提示信息,请勿应助】关于scihub 10000
Les Mantodea de Guyane: Insecta, Polyneoptera [The Mantids of French Guiana] 3000
徐淮辽南地区新元古代叠层石及生物地层 3000
The Mother of All Tableaux: Order, Equivalence, and Geometry in the Large-scale Structure of Optimality Theory 3000
Handbook of Industrial Diamonds.Vol2 1100
Global Eyelash Assessment scale (GEA) 1000
Picture Books with Same-sex Parented Families: Unintentional Censorship 550
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 遗传学 基因 物理化学 催化作用 冶金 细胞生物学 免疫学
热门帖子
关注 科研通微信公众号,转发送积分 4038184
求助须知:如何正确求助?哪些是违规求助? 3575908
关于积分的说明 11373872
捐赠科研通 3305715
什么是DOI,文献DOI怎么找? 1819255
邀请新用户注册赠送积分活动 892662
科研通“疑难数据库(出版商)”最低求助积分说明 815022