活性炭
Mercury(编程语言)
化学
吸附
氯
热解
氯化物
聚氯乙烯
无机化学
核化学
有机化学
计算机科学
程序设计语言
作者
Min Hui Lv,Guangqian Luo,Renjie Zou,Qingyu Ji,Can Fang,Wang Li,Xian Li,Hong Yao
出处
期刊:Fuel
[Elsevier]
日期:2022-04-20
卷期号:322: 124229-124229
被引量:20
标识
DOI:10.1016/j.fuel.2022.124229
摘要
Co-pyrolysis is a convenient method to load chloride on an adsorbent to improve its mercury removal ability. However, as a main reactive species, the formation mechanism of C-Cl functional groups remained unclear. In this study, the coconut shell activated carbon (AC) was co-pyrolyzed with polyvinyl chloride (PVC) to prepare a Cl-loading activated carbon, and it presented the best mercury removal efficiency (greater than 85%) at 140 °C. NO, O2 and HCl promoted the mercury removal ability of Cl-loading activated carbon, while SO2 inhibited. By comparing the performance of Cl-loading adsorbents using different Cl sources and supporters, we found that there were two formation paths for C-Cl functional groups. The first path was that some organic chlorine in PVC was reformed at low temperature (∼300 °C), and adhered to the surface of the adsorbent in the form of C-Cl functional groups. As the co-pyrolysis temperature increased, unstable C-Cl functional groups were decomposed and the mercury removal ability became weak. The second path was that the Cl first released out from PVC as gaseous HCl, and then combined with newly exposed carbon atom sites, which were generated owing to the devolatilization process of AC at high temperature (∼800 °C), to form C-Cl functional groups for mercury removal.
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