Electronic structure, upconversion luminescence and optical temperature sensing behavior of Yb3+-Er3+/Ho3+ doped NaLaMgWO6

光子上转换 分析化学(期刊) 荧光粉 激发 材料科学 兴奋剂 发光 相(物质) 带隙 化学 光电子学 物理 色谱法 量子力学 有机化学
作者
Jia Zhang,Jin Chen
出处
期刊:Journal of Alloys and Compounds [Elsevier]
卷期号:783: 84-94 被引量:65
标识
DOI:10.1016/j.jallcom.2018.12.281
摘要

To develop new upconversion (UC) phosphors of high sensitivity for temperature sensing, a series of Yb3+-Er3+ and Yb3+-Ho3+ doped NaLaMgWO6 (NLMW) samples were designed via solid-state reaction method. The phase purity was examined by XRD patterns, indicating the obtained samples are all single-phase. The morphology was characterized by SEM and TEM techniques, revealing smooth particle surface. The electronic structure of NLMW was analyzed theoretically, and the optical bandgap obtained was compared with the experimental results. Upon 980 nm excitation, the characteristic transitions of Er3+ and Ho3+ were found, and their optimal concentrations were determined to be 2 and 3 mol%, respectively. By investigating the temperature-dependence of NLMW:0.1 Yb3+,0.02Er3+, it was found that the thermally-coupled 2H11/2 and 4S3/2 levels of Er3+ cause a large fluorescence intensity ratio (FIR) for 528 and 550 nm emissions, which can generate a high absolute sensitivity (0.0107 K−1 at 508 K). The corresponding explanation was given by using the dependence of UC emissions on excitation power density. For the NLMW:0.1 Yb3+,0.03Ho3+ phosphor, the non-thermally-coupled (5F4,5S2) and 5F5 levels were employed to character the temperature-sensing behavior of Ho3+. High absolute sensitivity of 8.9×10−3 K−1 was gained at 548 K. The reason for the different change of 543 and 658 nm emissions intensities with temperature was conducted by the phonon-electron coupling.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
大幅提高文件上传限制,最高150M (2024-4-1)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
NexusExplorer应助日出采纳,获得10
2秒前
眠茶醒药完成签到,获得积分10
3秒前
4秒前
银子完成签到,获得积分20
4秒前
超级无敌大帅逼完成签到,获得积分10
6秒前
寒染雾发布了新的文献求助10
6秒前
7秒前
我爱小白贺完成签到,获得积分10
8秒前
8秒前
三寸光阴发布了新的文献求助10
9秒前
共享精神应助橙子采纳,获得10
10秒前
Jasper应助无情人达采纳,获得10
10秒前
123完成签到,获得积分10
10秒前
张叮当完成签到,获得积分20
10秒前
blue完成签到 ,获得积分10
10秒前
搜集达人应助shanbaibai采纳,获得10
11秒前
Hayat发布了新的文献求助10
11秒前
去看海嘛发布了新的文献求助10
12秒前
土豆发布了新的文献求助10
12秒前
传奇3应助keyan采纳,获得10
12秒前
研友_VZG7GZ应助八点必起采纳,获得10
13秒前
温温发布了新的文献求助10
14秒前
完美世界应助helong采纳,获得10
14秒前
顾矜应助vippp采纳,获得10
14秒前
14秒前
15秒前
Nancy完成签到 ,获得积分10
15秒前
备注完成签到,获得积分10
16秒前
轻松诗霜完成签到 ,获得积分10
17秒前
yycc发布了新的文献求助10
18秒前
要学习的小魏完成签到,获得积分10
19秒前
科研通AI2S应助小高采纳,获得10
19秒前
一一应助样子采纳,获得20
19秒前
19秒前
孟孟发布了新的文献求助10
20秒前
20秒前
20秒前
Lucas应助外向从灵采纳,获得10
21秒前
wu发布了新的文献求助10
21秒前
牛与马发布了新的文献求助20
21秒前
高分求助中
The late Devonian Standard Conodont Zonation 2000
Nickel superalloy market size, share, growth, trends, and forecast 2023-2030 2000
The Lali Section: An Excellent Reference Section for Upper - Devonian in South China 1500
Very-high-order BVD Schemes Using β-variable THINC Method 870
Mantiden: Faszinierende Lauerjäger Faszinierende Lauerjäger 800
PraxisRatgeber: Mantiden: Faszinierende Lauerjäger 800
A new species of Coccus (Homoptera: Coccoidea) from Malawi 500
热门求助领域 (近24小时)
化学 医学 生物 材料科学 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 基因 遗传学 催化作用 物理化学 免疫学 量子力学 细胞生物学
热门帖子
关注 科研通微信公众号,转发送积分 3256232
求助须知:如何正确求助?哪些是违规求助? 2898362
关于积分的说明 8300853
捐赠科研通 2567530
什么是DOI,文献DOI怎么找? 1394545
科研通“疑难数据库(出版商)”最低求助积分说明 652858
邀请新用户注册赠送积分活动 630522