Due to the excellent properties of graphene, including flexibility that allows it to adjust to the curvature of the substrate surface, chemical inertness, and impermeability, graphene is used as an anticorrosion layer. In this review, we present the current state-of-the-art in the application of graphene in the field of protective coatings. This review provides detailed discussions about the protective properties of graphene coatings deposited by different methods, graphene-based organic coatings, the modification of graphene-based coatings, and the effects of graphene functionalization on the corrosion resistance of protective coatings.