Strategic design of a bifunctional Ag(<scp>i</scp>)-grafted NHC-MOF for efficient chemical fixation of CO₂ from a dilute gas under ambient conditions

Facile grafting of catalytically active Ag( i ) into CO 2 -philic NHC-MOF for simultaneous capture and conversion of CO 2 from dilute gas to value-added α-alkylidene cyclic carbonate and oxazolidinones under mild conditions is demonstrated.