A Biomimetic Textile with Self-Assembled Hierarchical Porous Fibers for Thermal Insulation

Natural biomaterials with a porous structure inspired smart textiles for personal thermal management. Inspired by the hierarchically fibrous structure of hides, self-assembled hierarchical fibers with cross-scale porous networks are fabricated by the facile wet-spinning method. The biomimetic textile (abbreviated as "T") woven by such fibers exhibits a low thermal conductivity (0.07 W/mK) comparable to that of cowhide. It also shows a high mechanical strength of up to 10 MPa as well as good flexibility (fracture strain exceeds 300%) and hydrophobicity. The heat conduction mechanism of the hierarchical structure is analyzed via finite element simulation. When immersed with the phase-change material, the textile (named as "P") works like an adipose layer. Integration of the layers of T and P effectively slows down the heat conduction and decreases the surface temperature, resembling an animal insulation system. The study paves the way to mass production of high-performance biomimetic materials with hierarchical cellular microstructures for application in thermal insulation.