Experimental Study of Al-Modified Zeolite with Oxygen Nanobubbles in Repairing Black Odorous Sediments in River Channels

As an extreme phenomenon of water pollution, black odorous water not only causes ecological damage, but also severely restricts urban development. Presently, the in situ remediation technology for sediment from river channels is still undeveloped, and there are many bottlenecks in the key technologies for sediment pollution control and ecological restoration. In this study, three experimental tanks were used to explore the restoration effect of Al-modified zeolite with oxygen nanobubbles on black odorous sediment from the Shichuan River. One of the tanks housed Typha orientalis and Canna indica L. (TC), another tank housed the same plants and had Al-modified zeolite with oxygen nanobubbles (TC+AMZON), and the last tank was used as a comparison test (CS). The results show that the nitrogen (N) and phosphorus (P) in the sediment are violently released into the surrounding water. However, TC+AMZON could effectively inhibit the release of P. The released amount of soluble reactive phosphorus (SRP) from the pore water in the sediment reached its maximum at 40 d, and the amounts were 122.97% and 74.32% greater in TC and CS, respectively, than in TC+AMZON. However, the released amount of total phosphorus (TP) reached its maximum at 70 d, and the amounts were 260.14% and 218.23% greater in TC and CS, respectively, than in TC+AMZON. TC+AMZON significantly increased the dissolved oxygen (DO) and the oxidation-reduction potential (ORP) of pore water in the sediment in the early stages of the test. At 0 d, the DO content in TC+AMZON reached 10.6 mg/L, which is 112.0% and 178.95% greater than in TC and CS, respectively. The change law of ORP in the sediment is consistent with the DO. TC+AMZON significantly improved the transparency and reduced the content of chlorophylla in the upper water and could slightly reduce the N and P content in overlying water. The transparency of TC+AMZON increased by 130.76% and 58.73%, and chlorophylla decreased by 55.6% and 50.0% when compared to TC and CS, respectively.