Polystyrene-b-Poly(2-(Methoxyethoxy)ethyl Methacrylate) Polymerization by Different Controlled Polymerization Mechanisms

聚合 离子聚合 共聚物 高分子化学 可逆加成-断裂链转移聚合 链式转移 自由基聚合 链生长聚合 活性自由基聚合 活性聚合 聚苯乙烯 阴离子加成聚合 活性阴离子聚合 甲基丙烯酸酯 材料科学 聚合物 化学 有机化学
作者
Dragutin Nedeljković
出处
期刊:Polymers [MDPI AG]
卷期号:13 (20): 3505-3505
标识
DOI:10.3390/polym13203505
摘要

Functional polymers have been an important field of research in recent years. With the development of the controlled polymerization methods, block-copolymers of defined structures and properties could be obtained. In this paper, the possibility of the synthesis of the functional block-copolymer polystyrene-b-poly(2-(methoxyethoxy)ethyl methacrylate) was tested. The target was to prepare the polymer of the number average molecular weight (Mn) of approximately 120 that would contain 20-40% of poly(2-(methoxyethoxy)ethyl methacrylate) by mass and in which the polymer phases would be separated. The polymerization reactions were performed by three different mechanisms for the controlled polymerization-sequential anionic polymerization, atomic transfer radical polymerization and the combination of those two methods. In sequential anionic polymerization and in atomic transfer radical polymerization block-copolymers of the desired composition were obtained but with the Mn significantly lower than desired (up to 30). The polymerization of the block-copolymers of the higher Mn was unsuccessful, and the possible mechanisms for the unwanted side reactions are discussed. It is also concluded that combination of sequential anionic polymerization and atomic transfer radical polymerization is not suitable for this system as polystyrene macroinitiator cannot initiate the polymerization of poly(2-(methoxyethoxy)ethyl methacrylate).
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