催化作用
铜
浸出(土壤学)
材料科学
三元运算
球磨机
化学工程
选择性
金属
粒径
冶金
化学
有机化学
环境科学
计算机科学
土壤科学
工程类
土壤水分
程序设计语言
作者
Hezhi Liu,Yongjun Ji,Yongxia Zhu,Guangna Wang,Xueguang Wang,Ziyi Zhong,Fabing Su
出处
期刊:Particuology
[Elsevier]
日期:2017-08-31
卷期号:37: 1-8
被引量:10
标识
DOI:10.1016/j.partic.2017.05.008
摘要
In this work, we report a simple and inexpensive approach to synthesize effective multicomponent Cu–Cu2O–CuO catalysts for the Rochow process from industrial waste contact masses (WCMs). WCMs from the organosilane industry were treated with acid followed by reduction with metallic iron powder. The obtained copper powder was then subjected to controlled oxidation in air at different temperatures, followed by ball milling. The orthogonal array approach was applied to optimize this process, and the stirring speed and pH were found to significantly affect the leaching ratio and copper yield, respectively. When used for the Rochow process, the optimized ternary Cu–Cu2O–CuO catalyst greatly enhanced the dimethyldichlorosilane selectivity and Si conversion compared with Cu–Cu2O–CuO catalysts prepared without ball milling, bare Cu catalysts, and Cu–Cu2O–CuO catalysts with different compositions. This could be attributed to their small particle size and the strong synergistic effect among the multiple components in the catalyst with the optimized composition.
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