荧光
纳米传感器
量子产额
热液循环
检出限
猝灭(荧光)
离子强度
量子点
化学工程
荧光光谱法
材料科学
化学
碳纤维
分析化学(期刊)
水溶液
纳米技术
色谱法
光学
工程类
物理化学
物理
复合材料
复合数
作者
Huan Yang,Yuwei Long,Hong‐Xi Li,Shuang Pan,Hui Liu,Jidong Yang,Xiaoli Hu
标识
DOI:10.1016/j.jcis.2018.01.054
摘要
In this work, the carbon dots (CDs) were synthesized by an one-pot portable hydrothermal method from sodium citrate and NH4HCO3. The obtained CDs were found to show high fluorescence quantum yield (31%), excitation-wavelength independence, outstanding water-soluble, excellent chemical and optical stability. Interestingly, it was discovered that sunset yellow (SY) was sensitive and effective in quenching the fluorescence of CDs. Based on this observation, CDs could be applied as a novel fluoescent probe for detection of SY. The analytical potential of this probe was evaluated and illustrated a good linear relationship at the concentration range from 0.25 to 56.0 μmol L−1 with a detection limit (3σ/k) of 74.49 nmol L−1. Meanwhile, the practicality of this nanosensor for SY determination in real samples was validated with good accuracy and precision. In addtion, long time UV radiation and high ionic strength hardly influenced on the fluorescence intensity of CDs. However, the fluorescence intensity of CDs decreased at higher temperature and the fluorescence was recovered when temperature back to 5 °C. Therefore, CDs could be also employed as an fluorescent temperature sensor with significant sensitivity, linearity and remarkable reversibility.
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