氢气储存
材料科学
氢化镁
氢化物
催化作用
化学工程
球磨机
解吸
金属间化合物
氢
纳米材料
合金
共晶体系
吸附
冶金
纳米技术
金属
化学
吸附
有机化学
工程类
作者
Zahir Dehouche,H.A. Peretti,Yeong Yoo,Khaled Belkacemi,J. Goyette
出处
期刊:Recent Patents on Nanotechnology
日期:2009-06-01
卷期号:3 (2): 116-134
被引量:6
标识
DOI:10.2174/187221009788490059
摘要
Activated alloys synthesized by arc-melting were examined as catalysts for improving the hydrogen sorption characteristics of nanostructured magnesium hydride, proposed as a reversible hydrogen storage material. The MgH2- catalyst absorbing materials were prepared by ball milling of pure MgH2 with hydrided Zr47Ni53, Zr9Ni11, and other alloys investigated. The nanostructured MgH2-intermetallic systems were tested at 250°C and catalyst addition of eutectoid Zr47Ni53 resulted in the fastest desorption time and highest initial desorption rate. The catalyzed Mg-hydride with activated Zr9Ni11 and Zr7Ni10 phases showed fast desorption kinetics. Moreover, the results demonstrated that the composition of dispersed ZrxNiy catalysts has a strong influence on the amount of accumulated hydrogen and desorption rate of Mg-nanocomposite. Part two covers advanced micro-channels hydrogen storage module design based on the results of semi-empirical computer simulations of heat and mass transfers in the container. The micro-channels reservoir concept offers many advantages over the conventional metal hydride hydrogen storage system. It is a micro-structured system that can pack a lot of power into a small space and dissipate effectively the heat of the sorption reactions. This review summarize recent patents related to CNTS.
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