Recent Progress in Electrically Rechargeable Zinc–Air Batteries

Abstract Over the past decade, the surging interest for higher‐energy‐density, cheaper, and safer battery technology has spurred tremendous research efforts in the development of improved rechargeable zinc–air batteries. Current zinc–air batteries suffer from poor energy efficiency and cycle life, owing mainly to the poor rechargeability of zinc and air electrodes. To achieve high utilization and cyclability in the zinc anode, construction of conductive porous framework through elegant optimization strategies and adaptation of alternate active material are employed. Equally, there is a need to design new and improved bifunctional oxygen catalysts with high activity and stability to increase battery energy efficiency and lifetime. Efforts to engineer catalyst materials to increase the reactivity and/or number of bifunctional active sites are effective for improving air electrode performance. Here, recent key advances in material development for rechargeable zinc–air batteries are described. By improving fundamental understanding of materials properties relevant to the rechargeable zinc and air electrodes, zinc–air batteries will be able to make a significant impact on the future energy storage for electric vehicle application. To conclude, a brief discussion on noteworthy concepts of advanced electrode and electrolyte systems that are beyond the current state‐of‐the‐art zinc–air battery chemistry, is presented.