材料科学
复合材料
抗弯强度
艾氏冲击强度试验
纤维
聚酰胺
玻璃纤维
复合数
粘附
扫描电子显微镜
极限抗拉强度
作者
Shun Yang,Ying Wei,Hongfeng Yin,Dawei Li,Fei Xue
摘要
Abstract Interfacial adhesion properties are a key factor affecting the mechanical properties of composites. It is a very effective way to improve the low‐velocity impact resistance of composites by improving the interfacial adhesion properties. To improve the fiber/matrix interfacial adhesion properties of GF/PA6 (glass‐fiber/polyamide 6) composites, polyethyleneimine (PEI) and γ‐aminopropyltriethoxysilane (KH550) were used to co‐modify GF together in this study. The GF/PA6 composites with different modifications of glass‐fiber (GF) were also prepared using a hot pressing process, and then their flexural strength, shear strength, pendulum impact strength, and low‐speed impact resistance were investigated. Next, the relationship between fiber/matrix interfacial adhesion and mechanical properties of GF/PA6 composites was investigated by combining x‐ray photoelectron spectroscopy, scanning electron microscopy, and x‐ray computed tomography test results. The results showed that the GF‐reinforced PA6 matrix composite with co‐modified GF by PEI and KH550 (PEI‐KH550‐GF/PA6) had the best mechanical properties, with flexural, shear, and pendulum impact strengths of 660.7 MPa, 53.1 MPa, and 261.6 kJ/m 2 , respectively. Furthermore, the low‐velocity impact resistance was measured in terms of stress peak, absorbed energy, residual stress, and damage extension, and the results showed that the low‐speed impact resistance of PEI‐KH550‐GF/PA6 composites was also substantially improved that the F max increased from 7402.1 to 10414.0 N. Highlights Due to the poor surface activity of GF, in this experiment, GF was co‐modified with PEI and KH550 to achieve better fiber/matrix interfacial adhesion and successfully improve the mechanical properties of the composites; Different modification methods are used to improve the interfacial adhesion of the fiber/matrix interface. The relationship between the interface and impact strength of composites has been studied; The relationship between fiber/matrix interfacial adhesion and internal cracking in composites was investigated using X‐CT and SEM and other test results.
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