Cellulose separation from ramie bone by one step process with green hydrogen peroxide-citric acid

纤维素 结晶度 苎麻 化学 半纤维素 柠檬酸 过氧化氢 化学工程 环境友好型 有机化学 纤维 工程类 生态学 生物 结晶学
作者
Yuyang Wu,Chunxu Luo,Liqiong Li,Yixuan Jiang,Jinhan Yu,Tianjiao Wang,Jiarun Lu,Xinwang Cao,Wei Ke,Shengyu Li
出处
期刊:International Journal of Biological Macromolecules [Elsevier BV]
卷期号:267: 131444-131444 被引量:1
标识
DOI:10.1016/j.ijbiomac.2024.131444
摘要

Ramie bone (RB), an agricultural waste generated in the textile industry, is a vastly productive renewable natural resource with the potential to be used as a source of cellulose. In this study, ramie bone cellulose (RB-CE) was obtained in one step using a simple and ecologically friendly hydrogen peroxide-citric acid (HPCA) treatment procedure that avoided the use of halogenated reagents and strong acids while also streamlining the treatment processes. Various analytical methods were used to investigate the chemical composition and structure, crystallinity, morphology, thermal properties, surface area and hydration properties of cellulose separated at different treatment temperatures. HPCA successfully removed lignin and hemicellulose from RB, according to chemical composition analysis and FTIR. RB-CE had a type I cellulose crystal structure, and the crystallinity improved with increasing treatment temperature, reaching 72.51 % for RB-CE90. The RB-CE showed good thermal stability with degradation temperatures ranging from 294.2 °C to 319.1 °C. Furthermore, RB-CE had a high water/oil binding capacity, with RB-CE90 having WHC and OBC of 9.68 g/g and 7.24 g/g, respectively. The current work serves as a model for the environmentally friendly and convenient extraction of cellulose from biomass, and the cellulose obtained can be employed in the field of food and composite materials.
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